- Sandwich Shop Restaurants, Madisonville
- Seafood Restaurants, Madisonville
- Secondary Schools, Madisonville
- Secretarial & Court Reporting Services, Madisonville
- Security & Surveillance System & Equipment, Madisonville
- Security Brokers & Dealers, Madisonville
- Security Services, Madisonville
- Service & Gas Station Equipment & Services, Madisonville
- Sewer & Drain Cleaning & Repair, Madisonville - Drain Cleaner & Installation Services
- Sheet Metal Contractors, Madisonville - Sheet Metal Fabrication
- Sheet Metal Fabricators & Ductwork Contractors, Madisonville
- Ship & Boat Building & Repairing, Madisonville
- Shoe Stores, Madisonville - Mens, Womens & Kids Shoes
- Shopping & Shopping Services, Madisonville
- Small Appliances, Madisonville
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- Social Services & Welfare, Madisonville
- Societies & Foundation Associations, Madisonville
- Sound Systems, Microphones & Equipment, Madisonville
- Special Events & Party Supply Rental, Madisonville
- Specialty Animal Services, Madisonville
- Specialty Stores, Madisonville
- Specialty Vehicle Rental & Leasing, Madisonville
- Sporting Goods Stores, Madisonville
- State Government, Madisonville
- Steak House Restaurants, Madisonville
- Stocks & Bond Brokers, Madisonville
- Surveyor Services, Madisonville - Surveying Service
- Swimming Pool, Sauna & Spa Contractors, Madisonville
- Swimming Pools Contractors, Madisonville - Install Inground - Above Ground Pools
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